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Boomer May 1st 05 07:16 AM

I could not pass this up

"Then you posted
that RO water has a pH of 9 "

Get your head out of your dam ass

I said

Buy the way YOU may
want to tell some reefers who's RO/DI water is a pH of 8 or 9 that it is a real value. So,
you need to come to our Chem forum and explain that to Dr. Randy Holmes Farley who's RO/DI
pH is 9 !!!!!.

that pH is not real, it is a false reading just like others are, be
they 4, 6, 7, 7, 8.2 or what ever

I said it is NOT a real reading

In Dick & Jane terms, just for you. Just because the meter or kit says it is dose not mean
it is. If your meter says 9 or 5.4, it maybe really 4.7 or 5.9 or it may really be 5.4.
There is no way of knowing if the reading you get is true, hence a useless reading.
Special RO/DI sensors prove this when matched against std pH probes. What, no remarks on
the link I gave on measuring RO water with special RO/DI pH probes.Why the hell do you
think they make that dam things ? Do you think a chemical lab tech uses a std pH probe for
his RO water. Same for pH kits.


"I posted the fact that my RO water had a pH reading of 4.5. "

How do you know it is really 4.5...because a kit say so or that RO water often falls in
that range the kit must be right. That is like saying otter eats insects because their
stomach is full of them and someone say they never eat insects. Yah know what George,
their stomachs are full of insects but they never do eat insects, how did that
happen...get the point or are you lost still.


Good buy
--
Boomer

Want to talk chemistry ? The Reef Chemistry Forum
http://www.reefcentral.com/vbulletin/index.php


Former US Army Bomb Technician (EOD)
Member; IABTI, NATEODA, WEODF, ISEE & IPS

If You See Me Running You Better Catch-Up


"George" wrote in message
news:KLGce.29590$c24.28180@attbi_s72...
:
: "Boomer" wrote in message
: ...
: George you just like to get beat on don't you :-)
:
: Lets take these apart now
:
: "If there is nothing but pure water, then the pH will be 7. Are you saying
: that
: everytime one's pH gets close to 7 on the pH scale, we should ask for a refund
: from the manufacturer of our probes and pH kits?"
:
: THERE IS NO SUCH THING AS ABSOLUTE PURE WATER WITH A pH OF 7. The water that
: come closest
: is triple distilled water. Just because a sample of water has a pH 7 does not
: mean it is
: pure. My tap water is 7 and comes from a big lake. Where did you come up with
: this pH 7
: anyway ? pH is a function of temp, conductivity and mostly its CO2 and Alk. It
: goes like
: this, in Dick & Jane terms CO2 x Alk = pH. They are sometimes referred to as
: Buch-Park
: Equations. I have posted on them before here and extensively, do a search. You
: can have a
: pH of 7.00 with a low CO2 and Alk or a pH of 7.00 with a high CO2 and Alk, or
: for that
: mater a pH of 6, 8 ,9, pick one. I have them programmed in to my calculator,
: so when
: people ask what is my CO2 level if my pH is x and the Alk is y, as you can not
: measure CO2
: in seawater with any test kit, even if they say you can. There are also tables
: on the net
: on CO2 but only FW. B-P Eq. are given in many seawater chemistry books and I
: have about 10
: of them. I have talked to the worlds leading expert on the subject, Dr. Frank
: Milero, look
: his name up on a search engine. I also have his office phone number.
:
: Many test kits are inaccurate. Why do think people come here and to forums and
: say this; "
: I just bought another pH test kit.........MAD.......now I have three and one
: says pH 8.3,
: one 8.0 and the other 7.8, which one do I believe. It is a very, very common
: question
: George, same for other kits. Where did I say that as the meter/kit approaches
: pH 7 it is
: more inaccurate, no where. Quite dreaming things up :-)
:
:
: I realize that pH kits are innacurate. That is not the issue here. You said
: that pH is not real. If that were the case, then why bother ever measuring it?
:
: "So you are still insisting that RO water cannot be acidic, that it cannot
: contain CO2, and that it is all a myth of the pH meters? Hmmm. Some RO
: manufacturers think that you are full of bull****:"
:
: Where did I say RO water cannot be acidic George, no where, you just made that
: up, show me
: where ....a quote please.Where did I say RO water can not have CO2.
:
: I posted the fact that my RO water had a pH reading of 4.5. Do you remember
: your response, or do I have to juggle your memory? You said that "You CAN NOT
: measure the pH of RO/D water, there is nothing in the water to measure the pH.
: The readings are false, until it has some "salts" in it." And I've responded
: here that that is simply bonk, since RO water certainly does have something in
: it, especially if the source water contains CO2 in solution. Even RO
: manufacturers report that the pH of RO water is often low (i.e., 4-5). They do
: not say that the readings are false. They DO suggest that the reason for this
: is that CO2 in the source water will pass through the membrane, and that because
: there are no buffers in the water, the water will have a low pH. I've posted
: links to manufacturers web sites where they state this fact. Then you posted
: that RO water has a pH of 9 without ever explaining why this would be if all of
: the "salts" have been removed. If I was getting pH readings of 4.5 on time, and
: a pH of 9 another time, I would definitely believe that my pH measurements were
: way out of line. This has not been the case. My readings have been very
: consistent, regardless of whether I measure my salt water in my aquarium, the
: water from my tap, or the RO water. I can measure them repeatedly and get
: within 0.2 of the exact same readings every time.
:
: Quite reading into
: things they will get you in trouble. It is well known that RO water can be
: acidic and is
: the reason behind names like "aggressive water", "reactive water". I never
: said RO water
: had a pH that was not acid now did I , please give a quote. If you are going
: to make
: claims then quote it. I said a kit or meter can give false readings arcos the
: board. The
: readings are not reliably. So you want to post Spectra Pure's website yeh.
: Where on that
: website does it say what the expected pH of RO water is OR WHERE on that
: website do they
: tell you about measuring the pH of RO water. I wonder why that is.
:
: So George, if you have a RO unit with a TFM, 65 PSI of water pressure, a
: recovery rate of
: 4:1 and the tap water has 10 ppm CO2. how much of that CO2 gets through the
: membrane all
: or some or what. One of the biggest problems for most with RO/DI water, is
: that it sits in
: a container and gets exposed to ambient CO2, which just races into the water
: and lowers
: the pH
:
: I can and have taken readings as the water is being made up and still get
: 4.5-5.0.
:
: "Aeration or de-gassification of RO product water is recommended for removal
: of
: carbon dioxide"
:
: Well, I would hope so, especially that sitting
:
: I said this "RO water has virtually no CO2", that is why when it is exposed to
: ambient air
: the pH drops." That was in error somewhat, as RO water CO2 content, is a
: function of the
: tap water CO2 level and how much gets through the membrane. Also, "virtually
: no CO2" does
: not mean it can't lower the pH, as it does not take much with about 0 buffers.
:
: Ahem. This is what I said about 20 posts back.
:
: "All impurities will be rejected, but oxygen (O2) and CO2 that is a gas and
: smaller than the water molecule, will slip through the reverse osmosis
: membrane
: and affect the pH of the product water."
:
: Not all of the CO2 and O2 slips by and...... O2 has NO EFFECT on pH ....PERIOD
:
: Did you see this on your own link "Bitter/astringent - excess CO2 in RO water
: lowers pH",
: which means not all RO has excess CO2
:
: Why the hell would I care if other RO doesn't have excess CO2? And whether
: there is "excess" or not is not an issue. If there are no buffers, but CO2 is
: present, the pH will be low, which is the case with MY unit, and what I've been
: saying all though this thread.
:
:
:
: From George Slusarczuk
:
: "Hello Michael,
:
: You are absolutely right! Even among chemists it is a very little known
: fact, that the pH of distilled (and RO) water can not be measured. Let
: me correct that: It CAN be measured, but the value is meaningless! (That
: does NOT mean that distilled water has "no pH" -- just that we can not
: measure it using methods available to a hobbyist -- and that includes
: "research grade" electronic pH meters!)
:
:
http://www.finishing.com/258/08.shtml
:
: Here is some theory- H2O molecules have infinite resistance. It is ions that
: cause solutions to be conductive. Even perfectly pure water has some ions
: because of the equillibrium between H2O, H+ (ions), and OH- (ions). The
: concentration of the ions H+ and OH- in perfect water is 0.0000001 molar at 25º
: C. The pH of this water is exactly 7.
:
:



George May 1st 05 08:31 AM


"Benjamin" wrote in message
...
Very nice read guys!!!

George - Sounds like Boomer is already using large lag bolts to close your
coffin on this subject, why are you begging for him to weld it shut also? Your
not Houdini reincarnate are you? I'm seeing what he is saying as measuring
your RO water will give you meaningless measurements so there is not really a
point in doing it hence not a stable place to make water chemistry decisions
from, especially the sort you mention. Though I could be wrong and he may be
just exercising our minds and I'm confused.

Boomer- If I'm not still in your killfile... Cantankerous as ever, keep it up!
:-)

My question-
Could either of you explain the reasoning why many recommend using a balanced
additive to RO or RO/DI water prior to the addition of salt while others say
do it after? Are there chemical reaction reasons one way is better?


Thanks again,
--
--


I don't see that it makes any difference, really. Having said that, I would do
it after I I mixed up the sal****er, and tested the alkalinity to make sure that
I didn't add too much.



George May 1st 05 08:35 AM


"Boomer" wrote in message
...
Ben, I don't ever have anyone in my kill file, don't believe in it :-) I don't
even
remember why you would be there if I had one... lol

The balanced thing Ben is just hogwash, to get you to buy something.

I think George is just another troll. I see George likes to argue allot, and
not just me,
hence a troll. In one of his posts he even used the word he was a troll.


Excuse me? I was simply pointing out my experience in this area. Whether they
are correct or not is another matter. My use of the word troll was in reference
to you, not to me.

Just for ****s and giggles more of Georges' nonsense

"I think he meant malachite, which is a water-soluble form of copper
carbonate."


I never brought up malachite in any of my posts. Why are you making this crap
up?



George May 1st 05 08:38 AM


"Boomer" wrote in message
...
George there is no sense in continuing this, you seem to refuse anything and
everything,
which tells me you know you are incorrect but are trying to make an attempt to
make
yourself look good for the guys here.


"The guys here"? It seems that only you and one other have responded to this
thread in the last week. And looking good in front of you or anyone else is a
non-sequitur. But then, you already knew that.



Pszemol May 1st 05 04:57 PM

"George" wrote in message news:NH%ce.39388$r53.36575@attbi_s21...
"The guys here"? It seems that only you and one other have responded to this
thread in the last week. And looking good in front of you or anyone else is a
non-sequitur. But then, you already knew that.


The number of writers on any given newsgroups in any given thread
is much, much, much smaller than a number of readers...

Boomer May 2nd 05 06:43 AM

"I never brought up malachite in any of my posts. Why are you making this crap
up? "

I never make crap up George

Help needed to save a hippo tang 3/17/2005 2:04 AM
"George" wrote in message
news:k_9_d.144544$tl3.60629@attbi_s02...


"I think he meant malachite, which is a water-soluble form of copper carbonate."

Now that this thread seems to be dead, I hope, let me point out something I have been
waiting for you to see and you have missed it every time. No, I'm not picking on you. I
gave you the ammo to try and set me straight but you just missed it :-) You wanted to
come across as if you know stuff and sorry you don't.

In your post you say YOU have RO water, but you want to argue about pH of RO/DI water. All
of my posts are on what ....RO/DI water....and none till now on just RO water to set you
straight.. For all practical purposes RO/DI water is ultra-pure water and as your own
links show;

"It is nearly impossible to measure the pH of ultrapure water"

"You can not measure pH of ultrapure water with a pH sensor. There is not enough
conductivity for the sensor to work"

RO water IS NOT the same as RO/DI water. RO/DI water has a DI canister for further
filtration. RO water, coming from in lets say average tap water supply, will have about
5-10 ppm TDS, while RO/DI water will about 0 TDS. Measuring the pH of most home RO waters
is fine and yes you can believe the kit for most RO, as it still has enough ions on it. A
tap source of 200ppm TDS will still have a rejection rate from 95-98 % depending on the
membrane , line pressure, source water and temperature. 98 % of 200ppm TDS would be 5-10
ppm TDS sill left in the final RO water, enough to measure pH. As TDS goes down you start
to approach similar values of ultra-pure, with expensive high pressure RO units, where pH
measurement can be an issue.

Maybe next time you will listen rather than getting all wound up and getting things mixed
up. Don' think I haven't been there, we all have :-)



Have a nice day



--
Boomer

Want to talk chemistry ? The Reef Chemistry Forum
http://www.reefcentral.com/vbulletin/index.php


Former US Army Bomb Technician (EOD)
Member; IABTI, NATEODA, WEODF, ISEE & IPS

If You See Me Running You Better Catch-Up





Boomer May 2nd 05 06:53 AM

" And looking good in front of you or anyone else is a
non-sequitur"

I have done nothing but make you look bad and everyone knows it, including you. That is
part of the problem with a guy like you can't admit when wrong, you just try and put a
spin on things or miss-quote to make someone look bad and you correct. Guys like you
always hope that no one goes back to the other replies to see what is really said. This
will not bring respect to you but disrespect. This is why I always quote and admit when in
error.

--
Boomer

Want to talk chemistry ? The Reef Chemistry Forum
http://www.reefcentral.com/vbulletin/index.php


Former US Army Bomb Technician (EOD)
Member; IABTI, NATEODA, WEODF, ISEE & IPS

If You See Me Running You Better Catch-Up


"George" wrote in message
news:NH%ce.39388$r53.36575@attbi_s21...
:
: "Boomer" wrote in message
: ...
: George there is no sense in continuing this, you seem to refuse anything and
: everything,
: which tells me you know you are incorrect but are trying to make an attempt to
: make
: yourself look good for the guys here.
:
: "The guys here"? It seems that only you and one other have responded to this
: thread in the last week. And looking good in front of you or anyone else is a
: non-sequitur. But then, you already knew that.
:
:



George May 2nd 05 09:14 PM


"Boomer" wrote in message
...
"I never brought up malachite in any of my posts. Why are you making this
crap
up? "

I never make crap up George

Help needed to save a hippo tang 3/17/2005 2:04 AM
"George" wrote in message
news:k_9_d.144544$tl3.60629@attbi_s02...


"I think he meant malachite, which is a water-soluble form of copper
carbonate."


Yes, I said that, but was responding to what someone else said. I didn't bring
the subject up. So what is your point?

RO water IS NOT the same as RO/DI water. RO/DI water has a DI canister for
further
filtration.


No ****, sherlock.

RO water, coming from in lets say average tap water supply, will have about
5-10 ppm TDS, while RO/DI water will about 0 TDS. Measuring the pH of most
home RO waters
is fine and yes you can believe the kit for most RO, as it still has enough
ions on it.


Oh, so now you admit that I can take pH readings from MY RO unit (which has no
DI canister), and expect it to be accurate. Thanks for pointing out what I
already know.



George May 2nd 05 09:17 PM


"Boomer" wrote in message
...
" And looking good in front of you or anyone else is a
non-sequitur"

I have done nothing but make you look bad and everyone knows it, including
you.


And I didn't accuse you of doing so, did I?

That is
part of the problem with a guy like you can't admit when wrong,


Admit that I'm wrong? You just admitted in another post that I was right.

Quote:

"RO water IS NOT the same as RO/DI water. RO/DI water has a DI canister for
further
filtration. RO water, coming from in lets say average tap water supply, will
have about
5-10 ppm TDS, while RO/DI water will about 0 TDS. Measuring the pH of most home
RO waters
is fine and yes you can believe the kit for most RO, as it still has enough ions
on it."

Hello! That has been my argument all along, since my unit doesn't have a DI
canister.



Benjamin May 4th 05 11:26 PM

Thanks Boomer,

So the answer is it doesn't matter if you add buffers before or after mixing
the Salt mix to the Water?

I would have to guess he makes Chemical Tests?

--
--
--





"Boomer" wrote in message
...
Ben, I don't ever have anyone in my kill file, don't believe in it :-) I
don't even
remember why you would be there if I had one... lol

The balanced thing Ben is just hogwash, to get you to buy something.

I think George is just another troll. I see George likes to argue allot,
and not just me,
hence a troll. In one of his posts he even used the word he was a troll.

Just for ****s and giggles more of Georges' nonsense

"I think he meant malachite, which is a water-soluble form of copper
carbonate."

He is getting his heavy molecular weight organic-inorganic dyes, actually
a
triphenylmethane dye, use as a therapeutic agent. It is called Malachite
or Malachite
Green and he is getting it mixed up with Malachite, a cooper carbonate
hydroxide mineral.
Even didn't get that part right. Yet, he claims to have a master degree in
geology ... lol
It is called malachite only because it has a similar color to Malachite
the mineral. It
has 000000000 cooper in it.

But George wants to play chemist and geologist ..lol Now if George had any
smarts at all,
he would e-mail a real manufacture of RO units and ask them the question,
such as Dupont
or Osmonics, who make RO's. The ones people buy are just companies that
assemble parts,
like Spectra-Pure, they don 't really make anything. He could also come to
our chem forum
and ask Mr. Water Quality......GUESS Ben what he makes ????????????


--
Boomer

Want to talk chemistry ? The Reef Chemistry Forum
http://www.reefcentral.com/vbulletin/index.php


Former US Army Bomb Technician (EOD)
Member; IABTI, NATEODA, WEODF, ISEE & IPS

If You See Me Running You Better Catch-Up








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