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PH Crashed Damn what's going on Now!



 
 
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  #1  
Old February 24th 04, 08:21 AM
Kodiak
external usenet poster
 
Posts: n/a
Default PH Crashed Damn what's going on Now!

PH crashed in my 33gal three days ago.
stats were ammo 0, Nitrite 0, nitrate 10
but PH crashed to 6.0, KH was 0, kaput, nonexistant.
GH was very very low like 10. My Pleco died.

Did 50% water, PH only went up to 6.5, KH was still really bad.
Waited 12 hours and added 1 teaspoon baking soda.
PH went back up to 7.5 KH was 60 and GH 80. Fish got much
happier.

Today fish are acting all funny like they are hurting again.
Some are sitting on the bottom, most are bunched
together and hanging out near the filter inlet. Two of them
have minute signs of fin rot or look a bit frayed on the tips
that seems new. I rechecked stats all seems normal.
PH 7.5 KH 50, GH 60, ammo 0, nitrite0 nitrate10.
Did another 30% water tonight and they seem much happier
again.

Tank is a bit overstocked but it's been running a long time
and never had these problems. I'm running a good airstone,
an Aquaclear300 with lavarock and biomax media, temp is
72, i use 48hour airstone aged temp matched water with
recomended shot of dechlor. I also run a 0.05% salt solution.

I usually do a 30% water
with gravel siphon once a week. However, now i really
really siphon the gravel, I run a garden hose to the basement
so it really gets the krud out. My Nitrates are really low now,
always less than 10ppm. Could it be i'm overcleaning the gravel
and killing off good bacteria? If so shouldn't I see ammo or Nitrite
spike? Did the PH swing cause long term damage that will take a
while to recover? Did the PH swing hurt my biofilter? If so wouldn't
I see a spike?

Anyone have any idea what's going on here?

....Kodiak


  #2  
Old February 24th 04, 10:08 AM
Geezer From Freezer
external usenet poster
 
Posts: n/a
Default PH Crashed Damn what's going on Now!

not sure why your PH crashed in the first place, but your fish "might"
not be happy because you raised the PH too fast
  #3  
Old February 24th 04, 11:45 AM
Happy'Cam'per
external usenet poster
 
Posts: n/a
Default PH Crashed Damn what's going on Now!


Ive missed the beginning of this thread so I don't have the full picture but
why on earth are you missioning so badly with the ph???
STOP IT.....leave it alone. Your fish will be fine!!! Try and keep it stable
rather than adding all sorts of crap that keeps shifting it all over the
place. Thats why your fish are dying!!!!! Just say NO
--
**So long, and thanks for all the fish!**


"Kodiak" wrote in message
. ..
PH crashed in my 33gal three days ago.
stats were ammo 0, Nitrite 0, nitrate 10
but PH crashed to 6.0, KH was 0, kaput, nonexistant.
GH was very very low like 10. My Pleco died.

Did 50% water, PH only went up to 6.5, KH was still really bad.
Waited 12 hours and added 1 teaspoon baking soda.
PH went back up to 7.5 KH was 60 and GH 80. Fish got much
happier.

Today fish are acting all funny like they are hurting again.
Some are sitting on the bottom, most are bunched
together and hanging out near the filter inlet. Two of them
have minute signs of fin rot or look a bit frayed on the tips
that seems new. I rechecked stats all seems normal.
PH 7.5 KH 50, GH 60, ammo 0, nitrite0 nitrate10.
Did another 30% water tonight and they seem much happier
again.

Tank is a bit overstocked but it's been running a long time
and never had these problems. I'm running a good airstone,
an Aquaclear300 with lavarock and biomax media, temp is
72, i use 48hour airstone aged temp matched water with
recomended shot of dechlor. I also run a 0.05% salt solution.

I usually do a 30% water
with gravel siphon once a week. However, now i really
really siphon the gravel, I run a garden hose to the basement
so it really gets the krud out. My Nitrates are really low now,
always less than 10ppm. Could it be i'm overcleaning the gravel
and killing off good bacteria? If so shouldn't I see ammo or Nitrite
spike? Did the PH swing cause long term damage that will take a
while to recover? Did the PH swing hurt my biofilter? If so wouldn't
I see a spike?

Anyone have any idea what's going on here?

...Kodiak




  #4  
Old February 25th 04, 07:08 AM
Kodiak
external usenet poster
 
Posts: n/a
Default PH Crashed Damn what's going on Now!

What is "fine" about my Pleco dying?
I guess you missed that although it was in THIS post.
You also missed that i raised the PH slowly
over a 24 hour period, first 12 hours with a 50%
water, and another 12 hours with the soda.
I guess you also missed that the soda made the fish
much happier. If I took your advice, and that would be do
nothing when your PH crashes, my fish would probably
all be dead by now and i would be a happy camper NOT!...
read this....

http://www.koivet.com/html/articles/...ater%20Quality

....Kodiak

"Happy'Cam'per" wrote in message
...

Ive missed the beginning of this thread so I don't have the full picture

but
why on earth are you missioning so badly with the ph???
STOP IT.....leave it alone. Your fish will be fine!!! Try and keep it

stable
rather than adding all sorts of crap that keeps shifting it all over the
place. Thats why your fish are dying!!!!! Just say NO
--
**So long, and thanks for all the fish!**


"Kodiak" wrote in message
. ..
PH crashed in my 33gal three days ago.
stats were ammo 0, Nitrite 0, nitrate 10
but PH crashed to 6.0, KH was 0, kaput, nonexistant.
GH was very very low like 10. My Pleco died.

Did 50% water, PH only went up to 6.5, KH was still really bad.
Waited 12 hours and added 1 teaspoon baking soda.
PH went back up to 7.5 KH was 60 and GH 80. Fish got much
happier.

Today fish are acting all funny like they are hurting again.
Some are sitting on the bottom, most are bunched
together and hanging out near the filter inlet. Two of them
have minute signs of fin rot or look a bit frayed on the tips
that seems new. I rechecked stats all seems normal.
PH 7.5 KH 50, GH 60, ammo 0, nitrite0 nitrate10.
Did another 30% water tonight and they seem much happier
again.

Tank is a bit overstocked but it's been running a long time
and never had these problems. I'm running a good airstone,
an Aquaclear300 with lavarock and biomax media, temp is
72, i use 48hour airstone aged temp matched water with
recomended shot of dechlor. I also run a 0.05% salt solution.

I usually do a 30% water
with gravel siphon once a week. However, now i really
really siphon the gravel, I run a garden hose to the basement
so it really gets the krud out. My Nitrates are really low now,
always less than 10ppm. Could it be i'm overcleaning the gravel
and killing off good bacteria? If so shouldn't I see ammo or Nitrite
spike? Did the PH swing cause long term damage that will take a
while to recover? Did the PH swing hurt my biofilter? If so wouldn't
I see a spike?

Anyone have any idea what's going on here?

...Kodiak







  #5  
Old February 25th 04, 03:05 PM
external usenet poster
 
Posts: n/a
Default PH Crashed Damn what's going on Now!

unfortunately, the source you give is confused.
first of all, it doesnt take a lot of hydrogen ions to have the pH drop. In
distilled water there is no "buffer" so just a slight excess of H+ ions sends pH
spiraling downward. When there is a buffer present, the excess H+ hydrogen is
neutralized. The purpose of a buffer is to "resist" changes in the pH.
And rise in pH is due to an excess of OH- or hydroxide ions. Again, in distilled
water it doesnt take much OH to make the pH climb. And the buffer resist the change
in pH by neutralizing the excess OH-.
http://members.aol.com/BearFlag45/Bi...eviews/ph.html

The major source of CO2 in water is from the air. Rotting vegetation will put CO2
into the water because it is one end product of bacterial action. A plant that is
submerged will use up CO2 during the day and put out oxygen. At night it uses up
oxygen and puts out some CO2, but much less than it is using unless the plant is dead
and decaying. Plants that only have their roots in the water will not even put that
much CO2 into the water. CO2 cannot dissolve endlessly in water. At around pH 6.4 no
more net CO2 will dissolve in water it just goes in as a gas to a limited extent.
that is, it enters a steady state with CO2 going into solution and coming out of
solution at the same rate. Fish can do fine at pH 6.4.

What pushes the pH down below around pH 6.4 is the presence of organic acids. Dead
plant matter and feces that are undergoing anaerobic digestion by bacteria will
result in partially digested organic breakdown products. These are acidic and can
continue to build up as long as there are bacteria that can live at those acid
conditions. When there is an abundance of oxygen where bacteria are "working" they
will break organic matter down to CO2 and H2O plus other non-toxic compound.

Organic dolomitic limestone is a good source of buffer having both calcium and
magnesium. Oyster shells have almost no magnesium
http://www.eggcartons.com/item653.htm which is one reason they are used as grit for
chickens --- magnesium evidently inhibits egg laying. I put the ground up organic
limestone loose in my filter where it is dissolved as needed. Not everything that is
lime is safe. There are limes that are unstable and cause pH to swing up and down,
there are limes that just keep going into solution to high pH and kill fish.. like
quick lime. So always, always try a handful of the lime material in a gallon of tank
or pond water and test the pH over a couple days to make absolutely sure it is safe
to use.

When baking soda is put into acidic water CO2 is liberated. Put a LOT of baking soda
into a very acidic water and a LOT of CO2 is generated which means that until that
CO2 has time to out gas and leave the water it is very toxic to the fish. Fish are
no different than we are. We cannot have high levels of CO2 in the air even if there
is plenty of oxygen. Fish cannot have high levels of CO2 in the water even if there
is oxygen. It is important to slowly add the baking soda WITH plenty of aeration.
It is the aeration that moves the CO2 out of the water. Vigorous aeration that
breaks the surface speeds the release of excess CO2.

And the big point should be that it isnt just the increase in CO2, it is the lack of
oxygen in a system that results in the accumulation of organic acids that leads to
acidosis and death in fish. So this is why bare bottom tanks are so good. There is
no where for rotting organics to accumulate and be broken down anaerobically. Well,
unless the filter is a closed system. One reason I like my hang over the back
Whispers is the filter is open to the air.

You did right in raising the pH but with aeration you could have raised it much
faster. Changing the pH from acid to pH 7.0 will not cause big problems. They dont
undergo the same kind of shock as going from acid to alkaline, or alkaline to acid.
Baking soda is a temporary fix. You need to get the hardness up, a good buffering
system established. Ingrid


"Kodiak" wrote:
You also missed that i raised the PH slowly
over a 24 hour period, first 12 hours with a 50%
water, and another 12 hours with the soda.
I guess you also missed that the soda made the fish
much happier. If I took your advice, and that would be do
nothing when your PH crashes, my fish would probably
all be dead by now and i would be a happy camper NOT!...
read this....

http://www.koivet.com/html/articles/...ater%20Quality

...Kodiak



~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
List Manager: Puregold Goldfish List
http://puregold.aquaria.net/
www.drsolo.com
Solve the problem, dont waste energy finding who's to blame
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
Unfortunately, I receive no money, gifts, discounts or other
compensation for all the damn work I do, nor for any of the
endorsements or recommendations I make.
  #6  
Old February 26th 04, 05:23 AM
Kodiak
external usenet poster
 
Posts: n/a
Default PH Crashed Damn what's going on Now!

Thanks for all the info Ingrid, I have a descent airstone and big
Aquaclear300
for a tank that small (33gal) but I didn't want to chance it and get too
much CO2
in there so I raised it slowly. I will definitely look into the dolomitic
limestone as
you mentioned in the other post.
....Kodiak

wrote in message
...
unfortunately, the source you give is confused.
first of all, it doesnt take a lot of hydrogen ions to have the pH drop.

In
distilled water there is no "buffer" so just a slight excess of H+ ions

sends pH
spiraling downward. When there is a buffer present, the excess H+

hydrogen is
neutralized. The purpose of a buffer is to "resist" changes in the pH.
And rise in pH is due to an excess of OH- or hydroxide ions. Again, in

distilled
water it doesnt take much OH to make the pH climb. And the buffer resist

the change
in pH by neutralizing the excess OH-.
http://members.aol.com/BearFlag45/Bi...eviews/ph.html

The major source of CO2 in water is from the air. Rotting vegetation will

put CO2
into the water because it is one end product of bacterial action. A plant

that is
submerged will use up CO2 during the day and put out oxygen. At night it

uses up
oxygen and puts out some CO2, but much less than it is using unless the

plant is dead
and decaying. Plants that only have their roots in the water will not

even put that
much CO2 into the water. CO2 cannot dissolve endlessly in water. At

around pH 6.4 no
more net CO2 will dissolve in water it just goes in as a gas to a limited

extent.
that is, it enters a steady state with CO2 going into solution and coming

out of
solution at the same rate. Fish can do fine at pH 6.4.

What pushes the pH down below around pH 6.4 is the presence of organic

acids. Dead
plant matter and feces that are undergoing anaerobic digestion by bacteria

will
result in partially digested organic breakdown products. These are acidic

and can
continue to build up as long as there are bacteria that can live at those

acid
conditions. When there is an abundance of oxygen where bacteria are

"working" they
will break organic matter down to CO2 and H2O plus other non-toxic

compound.

Organic dolomitic limestone is a good source of buffer having both calcium

and
magnesium. Oyster shells have almost no magnesium
http://www.eggcartons.com/item653.htm which is one reason they are used

as grit for
chickens --- magnesium evidently inhibits egg laying. I put the ground up

organic
limestone loose in my filter where it is dissolved as needed. Not

everything that is
lime is safe. There are limes that are unstable and cause pH to swing up

and down,
there are limes that just keep going into solution to high pH and kill

fish.. like
quick lime. So always, always try a handful of the lime material in a

gallon of tank
or pond water and test the pH over a couple days to make absolutely sure

it is safe
to use.

When baking soda is put into acidic water CO2 is liberated. Put a LOT of

baking soda
into a very acidic water and a LOT of CO2 is generated which means that

until that
CO2 has time to out gas and leave the water it is very toxic to the fish.

Fish are
no different than we are. We cannot have high levels of CO2 in the air

even if there
is plenty of oxygen. Fish cannot have high levels of CO2 in the water

even if there
is oxygen. It is important to slowly add the baking soda WITH plenty of

aeration.
It is the aeration that moves the CO2 out of the water. Vigorous aeration

that
breaks the surface speeds the release of excess CO2.

And the big point should be that it isnt just the increase in CO2, it is

the lack of
oxygen in a system that results in the accumulation of organic acids that

leads to
acidosis and death in fish. So this is why bare bottom tanks are so good.

There is
no where for rotting organics to accumulate and be broken down

anaerobically. Well,
unless the filter is a closed system. One reason I like my hang over the

back
Whispers is the filter is open to the air.

You did right in raising the pH but with aeration you could have raised it

much
faster. Changing the pH from acid to pH 7.0 will not cause big problems.

They dont
undergo the same kind of shock as going from acid to alkaline, or alkaline

to acid.
Baking soda is a temporary fix. You need to get the hardness up, a good

buffering
system established. Ingrid


"Kodiak" wrote:
You also missed that i raised the PH slowly
over a 24 hour period, first 12 hours with a 50%
water, and another 12 hours with the soda.
I guess you also missed that the soda made the fish
much happier. If I took your advice, and that would be do
nothing when your PH crashes, my fish would probably
all be dead by now and i would be a happy camper NOT!...
read this....


http://www.koivet.com/html/articles/...cle_id=206&cat

egory=12&name=Water%20Quality

...Kodiak



~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
List Manager: Puregold Goldfish List
http://puregold.aquaria.net/
www.drsolo.com
Solve the problem, dont waste energy finding who's to blame
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
Unfortunately, I receive no money, gifts, discounts or other
compensation for all the damn work I do, nor for any of the
endorsements or recommendations I make.



  #7  
Old February 27th 04, 03:36 AM
Tom La Bron
external usenet poster
 
Posts: n/a
Default PH Crashed Damn what's going on Now!

Kodiak,

You may not be able to find Dolomite limestone, it is not carried just any
where any more. You used to able to buy it all the time for it was used as
a supplement for cattle and sheep, but about the only place you can find it
now are places where there is a lot of aquaculture facilities. If you can't
find it you may have to try oyster shells. I you have a feed store near you
can get oyster shell chicken grit, or if that is not available you can some
time go to the bird area of your local pet store and look for certain bird
grits. Wash it very good, for sometimes it is pretty dusty, and then put in
a bag made of nylon net from the yard good area of a sewing store or tulle.
Put the bag either in the discharge area of the filter or in the jump flow
of bubbles from you airstone.

Oyster shells keep my ponds between 80 and 129ppm of KH.

HTH

Tom L.L.
-----------------------------------

"Kodiak" wrote in message
...
Thanks for all the info Ingrid, I have a descent airstone and big
Aquaclear300
for a tank that small (33gal) but I didn't want to chance it and get too
much CO2
in there so I raised it slowly. I will definitely look into the dolomitic
limestone as
you mentioned in the other post.
...Kodiak

wrote in message
...
unfortunately, the source you give is confused.
first of all, it doesnt take a lot of hydrogen ions to have the pH drop.

In
distilled water there is no "buffer" so just a slight excess of H+ ions

sends pH
spiraling downward. When there is a buffer present, the excess H+

hydrogen is
neutralized. The purpose of a buffer is to "resist" changes in the pH.
And rise in pH is due to an excess of OH- or hydroxide ions. Again, in

distilled
water it doesnt take much OH to make the pH climb. And the buffer

resist
the change
in pH by neutralizing the excess OH-.
http://members.aol.com/BearFlag45/Bi...eviews/ph.html

The major source of CO2 in water is from the air. Rotting vegetation

will
put CO2
into the water because it is one end product of bacterial action. A

plant
that is
submerged will use up CO2 during the day and put out oxygen. At night it

uses up
oxygen and puts out some CO2, but much less than it is using unless the

plant is dead
and decaying. Plants that only have their roots in the water will not

even put that
much CO2 into the water. CO2 cannot dissolve endlessly in water. At

around pH 6.4 no
more net CO2 will dissolve in water it just goes in as a gas to a

limited
extent.
that is, it enters a steady state with CO2 going into solution and

coming
out of
solution at the same rate. Fish can do fine at pH 6.4.

What pushes the pH down below around pH 6.4 is the presence of organic

acids. Dead
plant matter and feces that are undergoing anaerobic digestion by

bacteria
will
result in partially digested organic breakdown products. These are

acidic
and can
continue to build up as long as there are bacteria that can live at

those
acid
conditions. When there is an abundance of oxygen where bacteria are

"working" they
will break organic matter down to CO2 and H2O plus other non-toxic

compound.

Organic dolomitic limestone is a good source of buffer having both

calcium
and
magnesium. Oyster shells have almost no magnesium
http://www.eggcartons.com/item653.htm which is one reason they are used

as grit for
chickens --- magnesium evidently inhibits egg laying. I put the ground

up
organic
limestone loose in my filter where it is dissolved as needed. Not

everything that is
lime is safe. There are limes that are unstable and cause pH to swing

up
and down,
there are limes that just keep going into solution to high pH and kill

fish.. like
quick lime. So always, always try a handful of the lime material in a

gallon of tank
or pond water and test the pH over a couple days to make absolutely sure

it is safe
to use.

When baking soda is put into acidic water CO2 is liberated. Put a LOT

of
baking soda
into a very acidic water and a LOT of CO2 is generated which means that

until that
CO2 has time to out gas and leave the water it is very toxic to the

fish.
Fish are
no different than we are. We cannot have high levels of CO2 in the air

even if there
is plenty of oxygen. Fish cannot have high levels of CO2 in the water

even if there
is oxygen. It is important to slowly add the baking soda WITH plenty of

aeration.
It is the aeration that moves the CO2 out of the water. Vigorous

aeration
that
breaks the surface speeds the release of excess CO2.

And the big point should be that it isnt just the increase in CO2, it is

the lack of
oxygen in a system that results in the accumulation of organic acids

that
leads to
acidosis and death in fish. So this is why bare bottom tanks are so

good.
There is
no where for rotting organics to accumulate and be broken down

anaerobically. Well,
unless the filter is a closed system. One reason I like my hang over

the
back
Whispers is the filter is open to the air.

You did right in raising the pH but with aeration you could have raised

it
much
faster. Changing the pH from acid to pH 7.0 will not cause big

problems.
They dont
undergo the same kind of shock as going from acid to alkaline, or

alkaline
to acid.
Baking soda is a temporary fix. You need to get the hardness up, a

good
buffering
system established. Ingrid


"Kodiak" wrote:
You also missed that i raised the PH slowly
over a 24 hour period, first 12 hours with a 50%
water, and another 12 hours with the soda.
I guess you also missed that the soda made the fish
much happier. If I took your advice, and that would be do
nothing when your PH crashes, my fish would probably
all be dead by now and i would be a happy camper NOT!...
read this....



http://www.koivet.com/html/articles/...cle_id=206&cat
egory=12&name=Water%20Quality

...Kodiak



~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
List Manager: Puregold Goldfish List
http://puregold.aquaria.net/
www.drsolo.com
Solve the problem, dont waste energy finding who's to blame
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
Unfortunately, I receive no money, gifts, discounts or other
compensation for all the damn work I do, nor for any of the
endorsements or recommendations I make.





  #8  
Old February 26th 04, 03:51 PM
Geezer From Freezer
external usenet poster
 
Posts: n/a
Default PH Crashed Damn what's going on Now!

Ingrid is spot on with that post.
  #9  
Old February 24th 04, 02:20 PM
external usenet poster
 
Posts: n/a
Default PH Crashed Damn what's going on Now!

when there is an inobvious problem with fish acting toxed out, or worse, fish dying
move the fish to a bucket of fresh water and then clean the tank out. your gravel
sounds like it has gone toxic. Jo Ann had every test known and she would get a
situation going where the fish were acting weird and NOTHING showed up on the tests
and she would just move the fish out to a new tank and she would empty and clean the
old one. some things cant be "figured out" in time to save the fish.
the longer any tank has been set up the more likely the tank has gone toxic somehow.
what kind of gravel you got?
Ingrid

"Kodiak" wrote:

PH crashed in my 33gal three days ago.
stats were ammo 0, Nitrite 0, nitrate 10
but PH crashed to 6.0, KH was 0, kaput, nonexistant.
GH was very very low like 10. My Pleco died.

Did 50% water, PH only went up to 6.5, KH was still really bad.
Waited 12 hours and added 1 teaspoon baking soda.
PH went back up to 7.5 KH was 60 and GH 80. Fish got much
happier.

Today fish are acting all funny like they are hurting again.
Some are sitting on the bottom, most are bunched
together and hanging out near the filter inlet. Two of them
have minute signs of fin rot or look a bit frayed on the tips
that seems new. I rechecked stats all seems normal.
PH 7.5 KH 50, GH 60, ammo 0, nitrite0 nitrate10.
Did another 30% water tonight and they seem much happier
again.

Tank is a bit overstocked but it's been running a long time
and never had these problems. I'm running a good airstone,
an Aquaclear300 with lavarock and biomax media, temp is
72, i use 48hour airstone aged temp matched water with
recomended shot of dechlor. I also run a 0.05% salt solution.

I usually do a 30% water
with gravel siphon once a week. However, now i really
really siphon the gravel, I run a garden hose to the basement
so it really gets the krud out. My Nitrates are really low now,
always less than 10ppm. Could it be i'm overcleaning the gravel
and killing off good bacteria? If so shouldn't I see ammo or Nitrite
spike? Did the PH swing cause long term damage that will take a
while to recover? Did the PH swing hurt my biofilter? If so wouldn't
I see a spike?

Anyone have any idea what's going on here?

...Kodiak




~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
List Manager: Puregold Goldfish List
http://puregold.aquaria.net/
www.drsolo.com
Solve the problem, dont waste energy finding who's to blame
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
Unfortunately, I receive no money, gifts, discounts or other
compensation for all the damn work I do, nor for any of the
endorsements or recommendations I make.
  #10  
Old February 25th 04, 07:22 AM
Kodiak
external usenet poster
 
Posts: n/a
Default PH Crashed Damn what's going on Now!

Thanks ingrid, i like where your going with this.
I have standard rainbow coulored Aquarium gravel,
bought it 5 years ago and been using it ever since
with no issues.

What I noticed that is weird is, i'll approach the tank
around feeding time, fish seem allright, they hang out at the
surface, i turn the lights on and feed them, they eat a bit,
then they dart around like mad and stop eating alltogether.
Could it be the black crud that accumulates on my aquarium
lid (i'm using egg crate material like the stuff to diffuse lights)
leaching back into the tank surface water? Is that stuff toxic?
Am I overcleaning the gravel? Is 10ppm Nitrates actually a
good thing?

I know the food is good cause I use it in my other tanks, no issues
with the other fish.

Still I suspect my water hardness is too low. My KH out of the tap
is around 30ppm or less, and when this whole thing started the PH crashed
and KH was 0, could toxins cause something like that?

....Kodiak


wrote in message
...
when there is an inobvious problem with fish acting toxed out, or worse,

fish dying
move the fish to a bucket of fresh water and then clean the tank out.

your gravel
sounds like it has gone toxic. Jo Ann had every test known and she would

get a
situation going where the fish were acting weird and NOTHING showed up on

the tests
and she would just move the fish out to a new tank and she would empty and

clean the
old one. some things cant be "figured out" in time to save the fish.
the longer any tank has been set up the more likely the tank has gone

toxic somehow.
what kind of gravel you got?
Ingrid

"Kodiak" wrote:

PH crashed in my 33gal three days ago.
stats were ammo 0, Nitrite 0, nitrate 10
but PH crashed to 6.0, KH was 0, kaput, nonexistant.
GH was very very low like 10. My Pleco died.

Did 50% water, PH only went up to 6.5, KH was still really bad.
Waited 12 hours and added 1 teaspoon baking soda.
PH went back up to 7.5 KH was 60 and GH 80. Fish got much
happier.

Today fish are acting all funny like they are hurting again.
Some are sitting on the bottom, most are bunched
together and hanging out near the filter inlet. Two of them
have minute signs of fin rot or look a bit frayed on the tips
that seems new. I rechecked stats all seems normal.
PH 7.5 KH 50, GH 60, ammo 0, nitrite0 nitrate10.
Did another 30% water tonight and they seem much happier
again.

Tank is a bit overstocked but it's been running a long time
and never had these problems. I'm running a good airstone,
an Aquaclear300 with lavarock and biomax media, temp is
72, i use 48hour airstone aged temp matched water with
recomended shot of dechlor. I also run a 0.05% salt solution.

I usually do a 30% water
with gravel siphon once a week. However, now i really
really siphon the gravel, I run a garden hose to the basement
so it really gets the krud out. My Nitrates are really low now,
always less than 10ppm. Could it be i'm overcleaning the gravel
and killing off good bacteria? If so shouldn't I see ammo or Nitrite
spike? Did the PH swing cause long term damage that will take a
while to recover? Did the PH swing hurt my biofilter? If so wouldn't
I see a spike?

Anyone have any idea what's going on here?

...Kodiak




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