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Bob
Sorry if I came out sounding like a horses ass, I usually don't realize it till later and it is to late. I spent a long time trying to fix this but it always doesn't work. Many of the guys here know what I mean -- Boomer Want to talk chemistry ? The Reef Chemistry Forum http://www.reefcentral.com/vbulletin/index.php Want to See More ? Please Join Our Growing Membership www.coralrealm.com If You See Me Running You Better Catch-Up "Boomer" wrote in message ... : Sorry, but you don't have clue what you are talking about. Seawater has a maximum Bc at a : pH of 6 & 9, as that is what its pKa is, so if the pH was 9 it would have the greatest : ability to withstand a pH shift, as half of the principal buffer is HCO3- and half is : CO3--. The HCO3- acts as the acid and CO3-- is the base. : : At any pH there is an exact ratio of CO2 + H20 : H2CO3 : HCO3 : CO3. As soon as RO/DI : water is exposed to air it will pick up CO2 and the pH will fall, the Alk will remain the : same. Below is how mixed bed resins work : : http://rip1.wwwcomm.com/resintech/Co...ell%2089-2.pdf : : : "Therefore the constant addition of : alkaline water which you trust to be pure DI water, and it no longer is, : slowly eats away at the tanks buffering capacity. Once the last of the : buffering salts covert to their basic form, the buffering is gone and the PH : starts creeping up." : : Lets be short, explain that in chemical terms and show any ref that states that from : chemical stand point.You won't find one will you. We are always adding basic ion's, such : OH- and is the reason behind adding kalk, Ca(OH)2 so the so called additon would be plus. : : Once the RO/DI water is exposed to air and once a seawater mix is added that water it is : buffered and has a pH, what ever it is and a buffering capacity and if it sits its : buffering doesn't change over time by magic.Finally, in a working seawater aquarium the pH : and "buffering capacity" are always working to the down side, low pH and low Alk unless : you add supplements to counter-react it. : : "I'm sorry but I've seen it happen on a very large scale where a plating tank : was destroyed because the DI water automatic top-off shifted the PH of the : tank." : : That is because you don't understand water chemistry, you are assuming and guessing. You : may want to look up some ref on plating water chemistry, there is tons out there. : : Here is a BIG start on reef water chemistry : : http://reefcentral.com/forums/showth...hreadid=102605 : : If you can't see this go here : : http://www.advancedaquarist.com/issues/may2002/chem.htm : : : I have been in this hobby for over 30 years. Most of my post on NG's and internet boards : ( see link below) are on water chemistry and I have yet seen any such thing as you claim. : That is because there is no such thing as you claim.....sorry. Feel free to come to our : chem. forum and post what you have said and see what kind of answers you get. I am not a : chemist, although many label me as one. There are a number of chemists on our board with : Ph D's in chemistry. The most well know is on the link above and moderates our forum on : the link below. All see the post on this NG to Tre' : : -- : Boomer : : Want to talk chemistry ? The Reef Chemistry Forum : http://www.reefcentral.com/vbulletin/index.php : : Want to See More ? : Please Join Our Growing Membership : www.coralrealm.com : : If You See Me Running You Better Catch-Up : : |
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